Thermal Equilibrium It is observed that a higher temperature object which is in contact with a lower temperature object will transfer heat to the lower temperature object. The objects will approach the same temperature, and in the absence of loss to other objects, they will then maintain a constant temperature. They are then said to be in thermal equilibrium. Thermal equilibrium is the subject of the Zeroth Law of Thermodynamics.

Zeroth Law of Thermodynamics

The "zeroth law" states that if two systems are at the same time in thermal equilibrium with a third system, they are in thermal equilibrium with each other.

If A and C are in thermal equilibrium with B, then A is in thermal equilibrium with B. Practically this means that all three are at the same temperature, and it forms the basis for comparison of temperatures. It is so named because it logically precedesthe First and Second Laws of Thermodynamics.